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A Comparison of Chemical Labeling Systems


Document Number: 198

OSHA’s 29 CFR 1910.1200 Hazard Communication Standard (Haz Com), also known as the “Right to Know” law, was first enacted on November 25, 1983 by OSHA.

The purpose of the standard is to protect workers from the chemicals they work with in their workplace. This standard requires training and the conveying of safety information to workers regarding the chemicals they come into contact with on the job.

These labels are required to contain specific information that apply to the chemicals used in the workplace;

1910.1200(f)(1)

“The chemical manufacturer, importer, or distributor shall ensure that each container of hazardous chemicals leaving the workplace is labeled, tagged or marked with the following information”

1910.1200(f)(1)(i)

“Identity of the hazardous chemical(s)”

1910.1200(f)(1)(ii)

“Appropriate hazard warnings; and”

1910.1200(f)(1)(iii)

“Name and address of the chemical manufacturer, importer, or other responsible party.”

1910.1200(f)(5)(ii)

“Appropriate hazard warnings, or alternatively, words, pictures, symbols, or combination thereof, which provide at least general information regarding the hazards of the chemicals, and which, in conjunction with the other information immediately available to employees under the hazard communication program, will provide employees with the specific information regarding the physical and health hazards of the hazardous chemical.”

Although the Haz Com standard sets only general guidelines for labeling it does specify that all labels must be in English. Bi-lingual chemical labels (i.e. English and Spanish) are allowed and offered as an option where a language barrier is present.

There are several labeling systems common to the workplace. These include:

RTK—Right to Know
NFPA 704/NFR National Fire Rating
HMIG—Hazardous Material Identification Guide
HMIS—Hazardous Material Identification System
WHMIS—Workplace Hazardous Material Information System (a Canadian based chemical identification labeling system)

This document's purpose is to identify the characteristics that each of these systems have to offer.

The RTK labeling system consists of labels that list the chemical name, synonym or common name, hazard information, CAS (Chemical Abstract Service) number and precautionary measures and first aid procedures. (See below)

NFPA 704 / NFR (National Fire Rating)

The National Fire Protection Association labeling system employs a color-coded rating guide in a diamond shape.

Health is defined by the color blue, Flammability is red and Instability is represented in yellow. The numbers are assigned according to the level of hazard the chemical(s) present 0-4. Thus 0 being no hazard and 4 the greatest hazard. This labeling option offers books, charts and wallet cards to help explain the classification.

NFR Signs are commonly seen on the exterior of a building or storage vessel containing chemical storage. In the event of a fire or emergency these signs alert the fire department or emergency responders to the types of chemical hazards that are present. See below for an example of this type of sign or label;

The HMIG labeling system also presents a color formatted label and is rectangular in shape. The numbers used in this system to identify the hazard level of the chemical are based on the acute and chronic hazards present in normal day to day use in the workplace. There are also charts, labels and wallet cards for this system. (For example see below)

The numbers for the HMIG labeling systems can be obtained from MSDS sheets accompanying the chemical or reference books that list chemical hazards by number rating such as The Fire Protection Guide to Hazardous Materials as well as the National Fire Rating Guide.

These three systems (RTK, NFR and HMIG) are all offered through Lab Safety Supply.

Another common labeling system similar to the HMIG system that Lab Safety Supply offers is called HMIS III. It is It looks similar in nomenclature to the HMIG labeling system (using the color bar format and rectangular shape) and utilizes a rating system similar to the HMIG system. HMIS III refers to Hazardous Materials Identification System. The HMIS III rating system has recently been revised. The most significant change to the label has been to the physical hazard section of the label. Along with the assigned number, an icon is now present: compressed gas, explosive, oxidizers, etc. This is to allow for easier identification of the presence of a specific hazard to the employee. (See an example below.)

WHMIS is the Canadian version of the OSHA Right To Know labeling system. WHMIS labels are required on all controlled products. A controlled product is defined as “a material or product, which is imported or sold in Canada that meets the guidelines of the hazardous material classification.” With this system the employer is required to educate and train their workers that are exposed to hazardous materials in their workplace. (See example below)

All of the above labeling systems (except WHMIS) are acceptable according to OSHA. However, once a system has been chosen, OSHA prefers to see consistency and that all chemicals are labeled according to the labeling program that has been chosen by the workplace. Also it is required that all employees must be trained to, and understand the system that is being implemented and used by the facility.

Commonly Asked Questions

Q. Is one of the labeling systems better than another?
A. No. One labeling system is not better than the other. OSHA recognizes all of these, however keep in mind consistency is the key. Once, you choose a system all chemicals should be labeled the same.
Q. I was told to buy an NFR Sign Kit to place outside of my building; How do I know what numbers should be assigned to the Health, Flammability, Instability and Special Hazards areas on this sign?
A. If you are in doubt about the hazard ratings for your NFR sign, it is best to check with your local authorities such as your local Fire Marshal to obtain the appropriate hazard ratings for your facility. They are able to make an assessment of the chemicals being used and/or stored and will be able to inform you how this sign should read for responders in the case of an emergency. For a general guide to chemical hazard labeling on common industrial chemicals LSS offers the 14683 Hazardous Materials NFR Pocket Guide.
Q. What do I put in the Special Hazards section of the NFR Labels and Signs?
A. Special Hazard symbols represent materials that offer a specific hazard such as an acid, corrosive, oxidizer, radiation or materials that react violently or explosively with water which are identified as water reactive chemicals. The Fire Protection Guide to Hazardous Materials (LSS PN# 5013) references these symbols and their meanings to this particular rating system.

Sources for More Information

OSHA's 29 CFR 1910.1200 Hazard Communication Standard
National Fire Protection Association

EZ FACTS Documents:
150 The Hazard Communication Standard
157 WHMIS-Canadian Right to Know System
178 NFPA 704 Standard System for the Identification of Hazardous Materials
200 Labeling for Hazard Communication

OSHA


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Please Note: The information contained in this publication is intended for general information purposes only. This publication is not a substitute for review of the applicable government regulations and standards, and should not be construed as legal advice or opinion. Readers with specific questions should refer to the cited regulation or consult with an attorney.
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